Differences and characteristics of HEC, HPMC, HEMC, and ...

Cellulose ether is a general term for the reaction of alkali cellulose and etherifying agent to produce a series of products under certain conditions. Alkaline cellulose is replaced by different etherifying agents to obtain different cellulose ethers. According to the ionization properties of substituents, cellulose ethers can be divided into two categories: ionic (such as carboxymethyl cellulose) and non-ionic (such as methyl cellulose). According to the types of substituents, cellulose ethers can be divided into mono-ethers (such as methyl cellulose) and mixed ethers (such as hydroxypropyl methyl cellulose). According to different solubility, it can be divided into water solubility (such as hydroxyethyl cellulose) and organic solvent solubility (such as ethyl cellulose). Dry-mix mortar mainly uses water-soluble cellulose, which is divided into instant type and delayed-dissolve type after surface treatment.

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The mechanism of action of cellulose ether in mortar is as follows:

(1) After the cellulose ether in the mortar is dissolved in water, the surface activity ensures that the gelling material is effectively and evenly distributed in the system. As a protective colloid, the cellulose ether "wraps" the solid particles and A layer of lubricating film is formed on the outer surface, which makes the mortar system more stable, and also improves the fluidity of the mortar during the mixing process and the smoothness of construction.

(2) The cellulose ether solution, due to its own molecular structure, makes the water in the mortar difficult to lose, and is gradually released over a long period of time, giving the mortar good water retention and workability.

 

1.    Methyl cellulose: (MC)

After the refined cotton is treated with alkali, chlorinated methane is used as an etherifying agent, and a series of reactions are carried out to produce cellulose ether. Generally, the degree of substitution is 1.6~2.0, and the solubility varies with the degree of substitution. Belongs to non-ionic cellulose ether.

(1) Methyl cellulose is soluble in cold water, and it is difficult to dissolve in hot water. Its aqueous solution is very stable in the range of pH=3~12. It has good compatibility with starch, guar gum, etc. and many surfactants. When the temperature reaches the gelation temperature, gelation will occur.

(2) The water retention of methyl cellulose depends on its addition, viscosity, particle fineness and dissolution rate. Generally, if the added amount is large, the fineness is small, and the viscosity is large, the water retention rate is high. Among them, the addition amount has the greatest influence on the water retention rate, and the viscosity is not proportional to the water retention rate. The dissolution rate mainly depends on the degree of surface modification of the cellulose particles and the fineness of the particles. Among the above cellulose ethers, methyl cellulose and hydroxypropyl methyl cellulose have higher water retention rates.

(3) The change of temperature will seriously affect the water retention rate of methyl cellulose. Generally, the higher the temperature, the worse the water retention. If the temperature of the mortar exceeds 40°C, the water retention of methyl cellulose will be significantly deteriorated, which will seriously affect the workability of the mortar.

(4) Methyl cellulose has a significant effect on the workability and adhesion of the mortar. The "adhesiveness" here refers to the adhesive force felt between the worker's application tool and the wall substrate, that is, the shear resistance of the mortar. The adhesiveness is large, the shear resistance of the mortar is large, and the force required by the workers in the use process is also large, and the workability of the mortar is poor. Among the cellulose ether products, the adhesion force of methyl cellulose is at a moderate level.

 

2.    Hydroxypropyl methylcellulose (HPMC)

Hydroxypropyl methylcellulose is a cellulose variety whose output and consumption have been increasing rapidly in recent years. It is a non-ionic cellulose mixed ether made from refined cotton through a series of reactions using propylene oxide and methyl chloride as etherification agents after alkalization treatment. The degree of substitution is generally 1.2~2.0. Its properties are different by the ratio of methoxy content and hydroxypropyl content.

(1) Hydroxypropyl methylcellulose is easily soluble in cold water, and it is difficult to dissolve in hot water. But its gelation temperature in hot water is significantly higher than that of methyl cellulose. The dissolution in cold water is also greatly improved compared to methyl cellulose.

(2) The viscosity of hydroxypropyl methylcellulose is related to its molecular weight, and the higher the molecular weight, the higher the viscosity. Temperature also affects its viscosity, as the temperature increases, the viscosity decreases. But its high viscosity has a lower temperature effect than methyl cellulose. The solution is stable when stored at room temperature.

(3) The water retention of hydroxypropyl methyl cellulose depends on its addition amount, viscosity, etc. The water retention rate under the same addition amount is higher than that of methyl cellulose.

(4) Hydroxypropyl methylcellulose is stable to acid and alkali, and its aqueous solution is very stable in the range of pH=2~12. Caustic soda and lime water do not have much impact on its performance, but alkali can speed up its dissolution rate and slightly increase its viscosity. Hydroxypropyl methylcellulose is stable to general salts, but when the concentration of the salt solution is high, the viscosity of the hydroxypropyl methylcellulose solution tends to increase.

(5) Hydroxypropyl methylcellulose can be mixed with water-soluble polymer compounds to form a uniform and higher viscosity solution. Such as polyvinyl alcohol, starch ether, vegetable glue and so on.

(6) Hydroxypropyl methyl cellulose has better enzyme resistance than methyl cellulose, and its enzymatic degradation possibility in solution is lower than that of methyl cellulose.

(7) The adhesion of hydroxypropyl methyl cellulose to mortar construction is higher than that of methyl cellulose.

 

3.    Hydroxyethyl cellulose (HEC)

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It is made by reacting refined cotton with ethylene oxide as an etherifying agent in the presence of acetone after alkali treatment. The degree of substitution is generally 1.5~2.0. It has strong hydrophilicity and is easy to absorb moisture.

(1) Hydroxyethyl cellulose is soluble in cold water, but it is difficult to dissolve in hot water. Its solution is stable at high temperature and does not have gelling properties. It can be used for a longer time under high temperature in the mortar, but its water retention is lower than that of methyl cellulose.

(2) Hydroxyethyl cellulose is stable to general acids and alkalis. Alkali can accelerate its dissolution and slightly increase its viscosity. Its dispersibility in water is slightly worse than that of methyl cellulose and hydroxypropyl methyl cellulose.

(3) Hydroxyethyl cellulose has good anti-sagging performance for mortar, but has a longer retardation time for cement.

(4) The performance of hydroxyethyl cellulose produced by some domestic enterprises is significantly lower than that of methyl cellulose due to its high-water content and high ash content.

 

4.    Carboxymethyl cellulose (CMC)

After alkali treatment of natural fibres (cotton, etc.), sodium mono-chloroacetate is used as an etherifying agent, and a series of reaction treatments are carried out to produce ionic cellulose ether. The degree of substitution is generally 0.4 to 1.4, and its performance is greatly affected by the degree of substitution.

(1) Carboxymethyl cellulose is highly hygroscopic, and it will contain a lot of moisture when stored under normal conditions.

(2) The carboxymethyl cellulose aqueous solution does not produce gel, and the viscosity decreases with the increase of temperature. When the temperature exceeds 50°C, the viscosity is irreversible.

(3) Its stability is greatly affected by pH. Generally, it can be used in gypsum-based mortar, but not in cement-based mortar. When it is highly alkaline, it loses its viscosity.

(4) Its water retention is much lower than that of methyl cellulose. It has retarding effect on gypsum-based mortar and reduces its strength. But the price of carboxymethyl cellulose is significantly lower than that of methyl cellulose.

Hydroxypropyl Methyl Cellulose (HPMC)

In recent years, the production and usage of Hydroxypropyl Methyl Cellulose (HPMC) have been increasing rapidly. Hydroxypropyl methyl cellulose is a non-ionic cellulose mixed ether made from refined cotton by alkalization treatment, using propylene oxide and chloromethane as etherizers, through various chemical reactions. The substitution degree of hydroxypropyl methylcellulose is generally 1.2~2.0, and its properties are different by the ratio of methoxy content and hydroxypropyl content. Specifically, you can learn about the &#;Effect of methoxy content and hydroxypropoxy content on HPMC&#;.

1. Hydroxypropyl methyl cellulose is easily soluble in cold water, and will encounter difficulties when dissolved in hot water. Its gelation temperature in hot water is significantly higher than that of methyl cellulose. The dissolution in cold water is also greatly improved compared to methyl cellulose.
2. The viscosity of hydroxypropyl methyl cellulose is related to its molecular weight, large molecular weight is high viscosity. Temperature also affects its viscosity, and the viscosity decreases when the temperature rises. However, its viscosity is less affected by temperature than that of methyl cellulose. Its solution is stable when stored at room temperature.
3. The water retention of hydroxypropyl methyl cellulose depends on its additive amount, viscosity, etc., and the water retention rate is higher than that of methyl cellulose under the same additive amount.
4. Hydroxypropyl methyl cellulose is stable to acid and alkali, and its aqueous solution is very stable in the range of pH=2~12. Caustic soda and lime water do not have much effect on its performance, but alkali can accelerate its dissolution rate. Hydroxypropyl methyl cellulose has stability to general salts, but when the concentration of salt solution is high, the viscosity of hydroxypropyl methyl cellulose solution will have a tendency to increase.
5. Hydroxypropyl methyl cellulose can be mixed with water-soluble polymer compounds to become uniform, higher viscosity solution. Such as polyvinyl alcohol, vegetable gum, etc.
6. Hydroxypropyl methyl cellulose has better enzyme resistance than methyl cellulose, and the possibility of enzymatic degradation of its solution is lower than that of methyl cellulose. Hydroxypropyl methyl cellulose adhesion to mortar construction is higher than methyl cellulose.

Methyl cellulose (MC)

Methyl cellulose is refined cotton treated with alkali and then made into cellulose ether through a series of reactions using methylene chloride as the etherifying agent. The general degree of substitution is 1.6~2.0, and the solubility varies with the degree of substitution. It belongs to non-ionic cellulose ether.

1. Methyl cellulose is soluble in cold water, hot water solubility will encounter difficulties, and its aqueous solution is very stable in the range of pH=3~12. It is compatible with starch, guanidinium gum, etc. and many surfactants. When the temperature reaches the gelation temperature, gelation will occur.
2. The water retention of methyl cellulose depends on its addition amount, viscosity, particle fineness and dissolution speed. Generally the larger the addition amount, the smaller the fineness and the larger the viscosity, the higher the water retention rate. The viscosity is not directly proportional to the water retention rate. The dissolution rate mainly depends on the degree of surface modification of cellulose particles and particle fineness. Among the several cellulose ethers introduced in this paper, methyl cellulose and hydroxypropyl methyl cellulose have higher water retention rates.
3. Changes in temperature can seriously affect the water retention of methyl cellulose. Generally the higher the temperature, the worse the water retention. If the mortar temperature exceeds 40 &#;, the water retention of methyl cellulose will be significantly worse, seriously affecting the constructability of mortar.
4. Methyl cellulose has a significant impact on the construction and adhesion of mortar. The &#;adhesion&#; refers to the adhesion between the applicator and the wall substrate, i.e. the shear resistance of the mortar. Adhesion is large, the shear resistance of the mortar is large, the force required by the workers in the process of application is also large, and the constructability of the mortar is poor. In the cellulose ether products methyl cellulose adhesion is at a medium level.

Hydroxyethyl cellulose (HEC)

Hydroxyethyl cellulose is made from refined cotton treated with alkali and reacted in the presence of acetone with ethylene oxide as the etherifying agent. Its substitution degree is generally 1.5~2.0. It has strong hydrophilicity and is easy to absorb moisture.

1. Hydroxyethyl cellulose can be dissolved in cold water, hot water is more difficult to dissolve. Its solution is stable at high temperature and does not have gelation. It can be used for a longer time in mortar under high temperatures, but the water retention is lower than methyl cellulose.
2. hydroxyethyl cellulose has the stability to general acid and alkali, alkali can accelerate its dissolution, and can slightly increase viscosity, its dispersion in water than methyl cellulose and hydroxypropyl methyl cellulose is slightly worse.
3. Hydroxyethyl cellulose has good performance on mortar anti-hanging, but the retardation time of cement is longer.
4. The performance of hydroxyethyl cellulose produced by some Chinese enterprises is significantly lower than that of methyl cellulose due to high water content and high ash content.

Carboxymethyl cellulose (CMC)

Carboxymethyl cellulose is made from natural fiber (cotton, etc.) after alkali treatment, with sodium monochloroacetate as the etherifying agent, after a series of reaction processing and made of ionic cellulose ether. Its substitution degree is generally 0.4~1.4, and the performance is greatly affected by the substitution degree.

1. Carboxymethyl cellulose is more hygroscopic and will contain more water when stored in general conditions.
2. Carboxymethyl cellulose aqueous solution will not produce gel, with the increase in temperature and viscosity decline, the temperature exceeds 50 &#;, the viscosity will be irreversible.
3. The stability of carboxymethyl cellulose is greatly affected by pH. Generally it can be used in gypsum-based mortar, not in cement-based mortar. At high alkalinity, it will lose viscosity.
4. The water retention of carboxymethyl cellulose is much lower than methyl cellulose. It has retardation effect on gypsum-based mortar and reduces its strength. However, the price of carboxymethyl cellulose is significantly lower than methyl cellulose.

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